Solution Thermodynamics and its Application to Aqueous Solutions

Written By Yoshikata Koga
Solution Thermodynamics and its Application to Aqueous Solutions
  • Publsiher : Elsevier
  • Release : 12 November 2007
  • ISBN : 9780080551876
  • Pages : 310 pages
  • Rating : /5 from reviews
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Download or read book entitled Solution Thermodynamics and its Application to Aqueous Solutions by author: Yoshikata Koga which was release on 12 November 2007 and published by Elsevier with total page 310 pages . This book available in PDF, EPUB and Kindle Format. As the title suggests, we introduce a novel differential approach to solution thermodynamics and use it for the study of aqueous solutions. We evaluate the quantities of higher order derivative than the normal thermodynamic functions. We allow these higher derivative data speak for themselves without resorting to any model system. We thus elucidate the molecular processes in solution, (referred to in this book “mixing scheme ), to the depth equal to, if not deeper, than that gained by spectroscopic and other methods. We show that there are three composition regions in aqueous solutions of non-electrolytes, each of which has a qualitatively distinct mixing scheme. The boundary between the adjacent regions is associated with an anomaly in the third derivatives of G. The loci of the anomalies in the temperature-composition field form the line sometimes referred as “Koga line . We then take advantage of the anomaly of a third derivative quantity of 1-propanol in the ternary aqueous solution, 1-propanol – sample species – H2O. We use its induced change as a probe of the effect of a sample species on H2O. In this way, we clarified what a hydrophobe, or a hydrophile, and in turn, an amphiphile, does to H2O. We also apply the same methodology to ions that have been ranked by the Hofmeister series. We show that the kosmotropes (salting out, or stabilizing agents) are either hydrophobes or hydration centres, and that chaotropes (salting in, or destablizing agents) are hydrophiles. A new differential approach to solution thermodynamics A particularly clear elucidation of the mixing schemes in aqueous solutions A clear understandings on the effects of hydrophobes, hydrophiles, and amphiphiles to H2O A clear understandings on the effects of ions on H2O in relation to the Hofmeister effect A new differential approach to studies in muti-component aqueous solutions

Solution Thermodynamics and its Application to Aqueous Solutions

Solution Thermodynamics and its Application to Aqueous Solutions
  • Author : Yoshikata Koga
  • Publisher : Elsevier
  • Release Date : 2007-11-12
  • Total pages : 310
  • ISBN : 9780080551876
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Summary : As the title suggests, we introduce a novel differential approach to solution thermodynamics and use it for the study of aqueous solutions. We evaluate the quantities of higher order derivative than the normal thermodynamic functions. We allow these higher derivative data speak for themselves without resorting to any model system. ...

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  • Publisher : Dowden Hutchinson and Ross
  • Release Date : 1976
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  • ISBN : 9780080551876
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Summary : Read online The Second Law of Thermodynamics written by Joseph Kestin, published by Dowden Hutchinson and Ross which was released on 1976. Download full The Second Law of Thermodynamics Books now! Available in PDF, ePub and Kindle....

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Summary : Read online U S Environmental Protection Agency Library System Book Catalog Holdings as of July 1973 written by United States. Environmental Protection Agency. Library Systems Branch, published by which was released on 1974. Download full U S Environmental Protection Agency Library System Book Catalog Holdings as of July 1973 Books now! Available in ...

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Summary : Read online Research and Development Progress Report written by United States. Office of Saline Water, published by which was released on 1965. Download full Research and Development Progress Report Books now! Available in PDF, ePub and Kindle....

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  • Author : Michael Modell,Administrative Director Department of Primary Health Care Michael Modell,Robert C. Reid
  • Publisher : Prentice Hall
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Summary : Read online Thermodynamics and Its Applications written by Michael Modell,Administrative Director Department of Primary Health Care Michael Modell,Robert C. Reid, published by Prentice Hall which was released on 1983. Download full Thermodynamics and Its Applications Books now! Available in PDF, ePub and Kindle....

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  • Release Date : 2009-06-17
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  • ISBN : 9780080551876
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Summary : This book consists of a number of papers regarding the thermodynamics and structure of multicomponent systems that we have published during the last decade. Even though they involve different topics and different systems, they have something in common which can be considered as the “signature” of the present book. First, ...

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  • ISBN : 9780080551876
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Summary : 1. Survey of the properties of water. 1.1. Introduction and some historical notes. 1.2. Properties of water in the gaseous phase. 1.3. Properties of water in the solid phase. 1.4. Properties of water in the liquid phase. 1.5. The Kirkwood-Buff integral. 1.6. Solvation of water in water. 1.7. The importance of water in biological systems -- 2. Theoretical approaches ...

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  • Publisher : John Wiley & Sons
  • Release Date : 2010-09-16
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  • ISBN : 9780080551876
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Summary : Expertise in electrolyte systems has become increasingly important in traditional CPI operations, as well as in oil/gas exploration and production. This book is the source for predicting electrolyte systems behavior, an indispensable "do-it-yourself" guide, with a blueprint for formulating predictive mathematical electrolyte models, recommended tabular values to use in ...

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  • Publisher : Unknown
  • Release Date : 1965
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  • ISBN : 9780080551876
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Summary : Read online Thermodynamics of Aqueous Solutions of Quaternary Ammonium Salts written by Wen-Yang Wen, published by which was released on 1965. Download full Thermodynamics of Aqueous Solutions of Quaternary Ammonium Salts Books now! Available in PDF, ePub and Kindle....

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  • Publisher : Unknown
  • Release Date : 1974
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Summary : Read online Thermodynamics of Aqueous Solutions Containing One Or More Volatile Weak Electrolytes written by Thomas James Edwards, published by which was released on 1974. Download full Thermodynamics of Aqueous Solutions Containing One Or More Volatile Weak Electrolytes Books now! Available in PDF, ePub and Kindle....

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Summary : Read online AIChE Symposium Series written by , published by which was released on 1984. Download full AIChE Symposium Series Books now! Available in PDF, ePub and Kindle....

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  • Author : Anonim
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