Some Observations on the Basic Chemistry of Plutonium

Written By E. S. Maxwell
Some Observations on the Basic Chemistry of Plutonium
  • Publsiher : Unknown
  • Release : 14 April 2021
  • ISBN :
  • Pages : 4 pages
  • Rating : /5 from reviews
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Download or read book entitled Some Observations on the Basic Chemistry of Plutonium by author: E. S. Maxwell which was release on 14 April 2021 and published by Unknown with total page 4 pages . This book available in PDF, EPUB and Kindle Format. On prolonged heating in dilute nitric acid (0.5M to 6.8M) a considerable amount of Pu(+4) is oxidized to Pu(+8). Precipitation of the plus three plutonium oxalate is complete in fifteen minutes. Oxidation of Pu(+4) to Pu(+8) by bromine is quantitative at 105 deg C after 1/2 hour; at 50 deg C the rate of oxidation is slow, but measurable. At room temperature the rate is too slow to measure. A method of converting PuC13 to Pu(NO3)4 is given. A solubility of NaPuO2Ac3 increases with temperature the value at 25 deg C being 19.5 g/iiter and that at 95 deg C, 37.5 g/liter. Supersaturation was observed on slow cooling of a saturated solution. p2.

Some Observations on the Basic Chemistry of Plutonium

Some Observations on the Basic Chemistry of Plutonium
  • Author : E. S. Maxwell
  • Publisher : Unknown
  • Release Date : 1948
  • Total pages : 4
  • ISBN :
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Summary : On prolonged heating in dilute nitric acid (0.5M to 6.8M) a considerable amount of Pu(+4) is oxidized to Pu(+8). Precipitation of the plus three plutonium oxalate is complete in fifteen minutes. Oxidation of Pu(+4) to Pu(+8) by bromine is quantitative at 105 deg C after 1/2 hour; at 50 deg C the rate ...

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