Alkene Polymerization Reactions with Transition Metal Catalysts

Written By Yury Kissin
Alkene Polymerization Reactions with Transition Metal Catalysts
  • Publsiher : Elsevier
  • Release : 10 March 2008
  • ISBN : 9780080557991
  • Pages : 495 pages
  • Rating : /5 from reviews
GET THIS BOOKAlkene Polymerization Reactions with Transition Metal Catalysts


Download or read book entitled Alkene Polymerization Reactions with Transition Metal Catalysts by author: Yury Kissin which was release on 10 March 2008 and published by Elsevier with total page 495 pages . This book available in PDF, EPUB and Kindle Format. During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands. 3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided the first reliable information about differences between various active centers in transition-metal catalysts. 4. A rapid development of high-resolution 13C NMR spectroscopy resulted in greatly expanded understanding of the chemical and steric features of polyolefins and alkene copolymers. These developments require a new review of all aspects of alkene polymerization reactions with transition-metal catalysts. The first chapter in the book is an introductory text for researchers who are entering the field. It describes the basic principles of polymerization reactions with transition-metal catalysts, the types of catalysts, and commercially manufactured polyolefins. The next chapter addresses the principal issue of alkene polymerization catalysis: the existence of catalyst systems with single and multiple types of active centers. The subsequent chapters are devoted to chemistry and stereochemistry of elemental reaction steps, structures of catalyst precursors and reactions leading to the formation of active centers, kinetics of polymerization reactions, and their mechanisms. The book describes the latest commercial polymerization catalysts for the synthesis of polyethylenes and polypropylene The book provides a detailed description of the multi-center nature of commercial Ziegler-Natta catalysts. The book devotes specialized chapters to the most important aspects of transition metal polymerization catalysts: the reactions leading to the formation of active centers, the chemistry and stereochemistry of elemental polymerization steps, reaction kinetics, and the polymerization mechanism. The book contains an introductory chapter for researchers who are entering the field of polymerization catalysis. It describes the basic principles of polymerization reactions with transition-metal catalysts and the types of commercially manufactured polyolefins and copolymers The book contains over 2000 references, the most recent up to end of 2006.

Alkene Polymerization Reactions with Transition Metal Catalysts

Alkene Polymerization Reactions with Transition Metal Catalysts
  • Author : Yury Kissin
  • Publisher : Elsevier
  • Release Date : 2008-03-10
  • Total pages : 495
  • ISBN : 9780080557991
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Summary : During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and ...

Handbook of Transition Metal Polymerization Catalysts

Handbook of Transition Metal Polymerization Catalysts
  • Author : Ray Hoff,Robert T. Mathers
  • Publisher : John Wiley & Sons
  • Release Date : 2010-09-16
  • Total pages : 640
  • ISBN : 9780080557991
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Summary : A one-stop resource for understanding and applying polymerization catalysts An edited volume featuring contributions from leading researchers, the Handbook of Transition Metal Polymerization Catalysts covers the design and synthesis of catalysts, and their applications in synthesis of polymers. Dealing with those polymerization catalysts that afford commercially acceptable yields of polymer ...

Late Transition Metal Polymerization Catalysis

Late Transition Metal Polymerization Catalysis
  • Author : Bernhard Rieger,Lisa Saunders Baugh,Smita Kacker,Susanne Striegler
  • Publisher : John Wiley & Sons
  • Release Date : 2006-03-06
  • Total pages : 345
  • ISBN : 9780080557991
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Summary : At the start of the 1950s, Ziegler and Natta discovered that simple metallorganic catalysts are capable of transforming olefins into linear polymers with highly ordered structures. This pioneering discovery was recognized with a Nobel Prize in 1963. In the 80s and 90s, the development of molecular defined metallocenes led to a ...

Transition Metal Catalyzed Polymerizations

Transition Metal Catalyzed Polymerizations
  • Author : Roderic P. Quirk
  • Publisher : Taylor & Francis
  • Release Date : 1983
  • Total pages : 886
  • ISBN : 9780080557991
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Summary : Read online Transition Metal Catalyzed Polymerizations written by Roderic P. Quirk, published by Taylor & Francis which was released on 1983. Download full Transition Metal Catalyzed Polymerizations Books now! Available in PDF, ePub and Kindle....

Comprehensive Organometallic Chemistry III

Comprehensive Organometallic Chemistry III
  • Author : Robert Crabtree
  • Publisher : Unknown
  • Release Date : 2007
  • Total pages : 9000
  • ISBN : 9780080557991
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Summary : Comprehensive Organometallic Chemistry, (COMC-III), Third Edition, 13 Volume Set is aimed at the specialist and non-specialist alike. It covers the major developments in the field in a carefully presented way with extensive cross-references. COMC-III provides a clear and comprehensive overview of developments since 1993 and attempts to predict trends in the field ...

Early Main Group Metal Catalysis

Early Main Group Metal Catalysis
  • Author : Sjoerd Harder
  • Publisher : John Wiley & Sons
  • Release Date : 2020-02-03
  • Total pages : 400
  • ISBN : 9780080557991
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Summary : Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain educational elements and deal with concepts illustrated by examples that cover the main developments. After a short introduction on polar organometallic chemistry and ...

Mechanistic Studies of Catalytic Alkene Polymerization and the Development of Stopped flow NMR Kinetics

Mechanistic Studies of Catalytic Alkene Polymerization and the Development of Stopped flow NMR Kinetics
  • Author : Matthew D. Christianson
  • Publisher : Unknown
  • Release Date : 2008
  • Total pages : 241
  • ISBN : 9780080557991
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Summary : Read online Mechanistic Studies of Catalytic Alkene Polymerization and the Development of Stopped flow NMR Kinetics written by Matthew D. Christianson, published by which was released on 2008. Download full Mechanistic Studies of Catalytic Alkene Polymerization and the Development of Stopped flow NMR Kinetics Books now! Available in PDF, ePub and ...

Direct Observation of Zirconocene catalyzed Alkene Polymerization Via NMR and the Role of an Aluminum Alkyl During Ploymerization

Direct Observation of Zirconocene catalyzed Alkene Polymerization Via NMR and the Role of an Aluminum Alkyl During Ploymerization
  • Author : Janice Hall Tomasik
  • Publisher : Unknown
  • Release Date : 2007
  • Total pages : 248
  • ISBN : 9780080557991
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Summary : Read online Direct Observation of Zirconocene catalyzed Alkene Polymerization Via NMR and the Role of an Aluminum Alkyl During Ploymerization written by Janice Hall Tomasik, published by which was released on 2007. Download full Direct Observation of Zirconocene catalyzed Alkene Polymerization Via NMR and the Role of an Aluminum Alkyl During ...

Transition Metal Catalysis in Macromolecular Design

Transition Metal Catalysis in Macromolecular Design
  • Author : Lisa Saunders Boffa,Bruce M. Novak
  • Publisher : Amer Chemical Society
  • Release Date : 2000
  • Total pages : 299
  • ISBN : 9780080557991
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Summary : Metal-mediated polymerization is fast becoming an essential tool for the fine control of macromolecular architecture. Advanced Catalysis demonstrates how the field of transition metal-catalyzed polymer syntheses has moved beyond the simple use of single-site catalysts to new applications and "advanced" techniques of architectural control. This book defines and presents "next ...

Proceedings of the National Academy of Sciences of the United States of America

Proceedings of the National Academy of Sciences of the United States of America
  • Author : National Academy of Sciences (U.S.)
  • Publisher : Unknown
  • Release Date : 2006
  • Total pages : 212
  • ISBN : 9780080557991
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Summary : Read online Proceedings of the National Academy of Sciences of the United States of America written by National Academy of Sciences (U.S.), published by which was released on 2006. Download full Proceedings of the National Academy of Sciences of the United States of America Books now! Available in PDF, ePub ...

Solution Structures of Two Homogeneous Early Transition metal Olefin Polymerization Catalysts

Solution Structures of Two Homogeneous  Early Transition metal  Olefin Polymerization Catalysts
  • Author : John Monteval Wright
  • Publisher : Unknown
  • Release Date : 1997
  • Total pages : 398
  • ISBN : 9780080557991
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Summary : Read online Solution Structures of Two Homogeneous Early Transition metal Olefin Polymerization Catalysts written by John Monteval Wright, published by which was released on 1997. Download full Solution Structures of Two Homogeneous Early Transition metal Olefin Polymerization Catalysts Books now! Available in PDF, ePub and Kindle....

Synthesis and Development of Bidentate 3 4 diazaphospholanes for Metal catalyzed Reactions

Synthesis and Development of Bidentate 3 4 diazaphospholanes for Metal catalyzed Reactions
  • Author : Brian G. Hashiguchi
  • Publisher : Unknown
  • Release Date : 2008
  • Total pages : 287
  • ISBN : 9780080557991
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Summary : Read online Synthesis and Development of Bidentate 3 4 diazaphospholanes for Metal catalyzed Reactions written by Brian G. Hashiguchi, published by which was released on 2008. Download full Synthesis and Development of Bidentate 3 4 diazaphospholanes for Metal catalyzed Reactions Books now! Available in PDF, ePub and Kindle....

Step growth Polymers for High performance Materials

Step growth Polymers for High performance Materials
  • Author : James L. Hedrick,American Chemical Society,Jeff W. Labadie,American Chemical Society. Division of Polymer Chemistry,American Chemical Society. Meeting,Calif.) American Chemical Society Meeting 1995 (Anaheim
  • Publisher : Amer Chemical Society
  • Release Date : 1996
  • Total pages : 469
  • ISBN : 9780080557991
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Summary : Presents the latest work in transition metal catalyzed polymerization, dendritic and hyperbranched systems, poly(aryl ether) synthesis, polyimides, and high-temperature polymers. Describes recent research on commercially important polymers based on step-growth polymerization. Includes well-referenced overview articles that review step-growth polymerization and indicate how individual research papers have impacted the field....

Inorganic Reactions and Methods Formation of bonds to transition and inner transition metals

Inorganic Reactions and Methods  Formation of bonds to transition and inner transition metals
  • Author : Anonim
  • Publisher : Unknown
  • Release Date : 1986
  • Total pages : 212
  • ISBN : 9780080557991
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Summary : Read online Inorganic Reactions and Methods Formation of bonds to transition and inner transition metals written by , published by which was released on 1986. Download full Inorganic Reactions and Methods Formation of bonds to transition and inner transition metals Books now! Available in PDF, ePub and Kindle....

Introduction to Polymer Chemistry Second Edition

Introduction to Polymer Chemistry  Second Edition
  • Author : Charles E. Carraher Jr.
  • Publisher : CRC Press
  • Release Date : 2010-01-12
  • Total pages : 510
  • ISBN : 9780080557991
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Summary : With an emphasis on the environment and green chemistry and materials, this second edition offers detailed coverage of natural and synthetic giant molecules, inorganic and organic polymers, elastomers, adhesives, coatings, fibers, plastics, ceramics, and more....